In which of the following reactions is $K_p > K_c$ at $10 \ K$ temperature?

  • A
    $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$
  • B
    $2HI_{(g)} \rightleftharpoons H_{2(g)} + I_{2(g)}$
  • C
    $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$
  • D
    None of these

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For the reaction $2NOCl_{(g)} \rightleftharpoons 2NO_{(g)} + Cl_{2_{(g)}}$ at $1060 \ K$,the equilibrium constant $K_p$ is $0.033 \ atm$. Find the value of $K_c$. (Given $R = 0.082 \ L \ atm \ K^{-1} \ mol^{-1}$)

Consider the equilibria $(i)$ and $(ii)$ with equilibrium constants $K_1$ and $K_2$,respectively.
$SO_{2(g)} + 1/2 O_{2(g)} \rightleftharpoons SO_{3(g)} ..... (i)$
$2 SO_{3(g)} \rightleftharpoons 2 SO_{2(g)} + O_{2(g)} ..... (ii)$
$K_1$ and $K_2$ are related as

For the reaction $2NOCl_{(g)} \rightleftharpoons 2NO_{(g)} + Cl_{2(g)}$,$K_C$ at $427\ ^oC$ is $3 \times 10^{-6}\ mol\ L^{-1}$. The value of $K_P$ is nearly $....... \times 10^{-4}$.

For the reactions:
$2NO + O_2 \rightleftharpoons 2NO_2$; $K_1$
$4NO + 2Cl_2 \rightleftharpoons 4NOCl$; $K_2$
$NO_2 + \frac{1}{2}Cl_2 \rightleftharpoons NOCl + \frac{1}{2}O_2$; $K_3$
Where $K_1, K_2, K_3$ are equilibrium constants,then $K_3^2$ is equal to:

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At $413 \ K$ temperature and $100 \ atm$ pressure,$1 \ mol$ $N_2$ and $3 \ mol$ $H_2$ are heated in a closed vessel. At equilibrium,$0.50 \ mol$ $NH_3$ is present. Find $K_p$.

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