Match List-$I$ with List-$II$.
List-$I$:
$(a)$ $\text{Benzene} \xrightarrow[\text{CuCl}]{\text{CO, HCl, Anhyd. AlCl}_3} \text{Benzaldehyde}$
$(b)$ $R-CO-CH_3 + NaOX \rightarrow$
$(c)$ $R-CH_2-OH + R'COOH \xrightarrow{\text{Conc. H}_2\text{SO}_4}$
$(d)$ $R-CH_2COOH \xrightarrow[(ii) H_2O]{(i) X_2/\text{Red P}} R-CH(X)COOH$
List-$II$:
$(i)$ $\text{Hell-Volhard-Zelinsky reaction}$
(ii) $\text{Gattermann-Koch reaction}$
(iii) $\text{Haloform reaction}$
(iv) $\text{Esterification}$
Choose the correct answer from the options given below.

  • A
    $(a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)$
  • B
    $(a)-(iii), (b)-(ii), (c)-(i), (d)-(iv)$
  • C
    $(a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)$
  • D
    $(a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)$

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Identify $Z$ in the following reaction sequence:
$CH_3COONH_4$ $\xrightarrow{\Delta} X$ $\xrightarrow{P_2O_5} Y$ $\xrightarrow{H_2O/H^+} Z$

The end product of the above reaction is:

$CH_3-C(=O)-OH$ $\xrightarrow{NaH^{14}CO_3} (A) (\text{gas})$ $\xrightarrow[(ii) H_3O^{+}]{(i) PhMgBr} (B)$
$CH_3-S(=O)_2-OH$ $\xrightarrow{NaH^{14}CO_3} (C) (\text{gas})$ $\xrightarrow[(ii) H_3O^{+}]{(i) PhMgBr} (D)$
Product $(B)$ and $(D)$ in the above reaction are:

An organic acid $P$ $(C_{11}H_{12}O_2)$ can easily be oxidized to a dibasic acid which reacts with ethylene glycol to produce a polymer,dacron. Upon ozonolysis,$P$ gives an aliphatic ketone as one of the products. $P$ undergoes the following reaction sequences to furnish $R$ via $Q$. The compound $P$ also undergoes another set of reactions to produce $S$.
$(1)$ The compound $R$ is
$(2)$ The compound $S$ is
Give the answer for questions $(1)$ and $(2)$.

The reaction sequence is:
$2-\text{hydroxycyclohexylacetone}$ $\xrightarrow{I_2/NaOH}$ $\xrightarrow{\Delta}$ $\xrightarrow{H^+}$ $\xrightarrow{\Delta} A$
$A$ is:

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