Match the compounds in List-$I$ with the observations in List-$II$,and choose the correct option.
List-$I$ List-$II$
$I$. Aniline $P$. Sodium fusion extract of the compound on boiling with $FeSO_4$,followed by acidification with conc. $H_2SO_4$,gives Prussian blue color.
$II$. $o$-Cresol $Q$. Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color.
$III$. Cysteine $R$. Addition of the compound to a saturated solution of $NaHCO_3$ results in effervescence.
$IV$. Caprolactam $S$. The compound reacts with bromine water to give a white precipitate.
$T$. Treating the compound with neutral $FeCl_3$ solution produces violet color.

  • A
    $I$ $\rightarrow P, Q; II$ $\rightarrow S; III$ $\rightarrow Q, R; IV$ $\rightarrow P$
  • B
    $I$ $\rightarrow P; II$ $\rightarrow R, S; III$ $\rightarrow R; IV$ $\rightarrow Q, S$
  • C
    $I$ $\rightarrow Q, S; II$ $\rightarrow P, T; III$ $\rightarrow P; IV$ $\rightarrow S$
  • D
    $I$ $\rightarrow P, S; II$ $\rightarrow T; III$ $\rightarrow Q, R; IV$ $\rightarrow P$

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Similar Questions

Consider the following table$-$
Column-$I$ Column-$II$
$A$. Best and latest technique for isolation,purification and separation of organic compounds $i$. Chromatography
$B$. In Lassaigne's test for $N$ $ii$. Vacuum distillation
$C$. In Lassaigne's test for $S$ $iii$. Violet coloured complex is formed
$D$. Aniline is separated from water by $iv$. Prussian blue coloured complex is formed
$E$. Glycerol is purified from spent lye $v$. Steam distillation

The correct match is$-$

In the test for halogens,why is nitric acid added to the sodium fusion extract before adding silver nitrate?

How are carbon and hydrogen detected in an organic compound? Explain with reactions.

Given below are two statements :
Statement $I :$ In Lassaigne's test,the covalent organic molecules are transformed into ionic compounds.
Statement $II :$ The sodium fusion extract of an organic compound having $N$ and $S$ gives prussian blue colour with $FeSO_4$ and $FeCl_3$.
In the light of the above statements,choose the correct answer from the options given below.

Assertion : During the test for nitrogen with Lassaigne's extract,on adding $FeCl_3$ solution,sometimes a blood-red coloration is obtained.
Reason : Sulphur is also present along with nitrogen in the organic compound.

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