On diluting the concentration of $Cl^{-}$ ions by ten times in a calomel electrode,its reduction potential at $298 \ K$ is -

Fill in the blanks :
$1.$ The ratio of concentration of products to concentration of reactants is ........
$2.$ $\ln(\log(x)) =$ ............
$3.$ At equilibrium,between $E_{cell}$ and $E_{cell}^{o}$,......... will be zero.

$A$ hydrogen electrode is made by dipping platinum wire in a solution of nitric acid of $pH=9$ and passing hydrogen gas around the platinum wire at $1.2 \ atm$ pressure. The oxidation potential of such an electrode equals $V$.

The logarithm of the equilibrium constant for the reaction $Pd^{2+}{(aq)} + 4Cl^{-}{(aq)} \rightleftharpoons PdCl_4^{2-}{(aq)}$ is (Nearest integer).
Given: $\frac{2.303 RT}{F} = 0.06 \ V$
$Pd^{2+}{(aq)} + 2e^{-} \rightleftharpoons Pd_{(s)} \quad E^{\circ} = 0.83 \ V$
$PdCl_4^{2-}{(aq)} + 2e^{-} \rightleftharpoons Pd_{(s)} + 4Cl^{-}{(aq)} \quad E^{\circ} = 0.65 \ V$

The magnitude of the change in oxidising power of the $MnO_4^- / Mn^{2+}$ couple is $x \times 10^{-4} \, V$,if the $H^{+}$ concentration is decreased from $1 \, M$ to $10^{-4} \, M$ at $25^{\circ} C$. (Assume concentration of $MnO_4^-$ and $Mn^{2+}$ to be same on change in $H^{+}$ concentration). The value of $x$ is ....... .
(Rounded off to the nearest integer)
$[\text{Given} : \frac{2.303 RT}{F} = 0.059]$

What minimum decomposition potential is necessary to produce $Cl_2$ gas in the following reaction?
Given: $(\frac{2.303RT}{F} = 0.06)$
$Sn^{+2} (1 \ M) + 2Cl^{-} (2 \ M) \rightleftharpoons Sn_{(s)} + Cl_2 (1 \ atm)$
Given: $E^{o}_{Sn^{+2}/Sn} = -0.14 \ V$,$E^{o}_{Cl_2/Cl^{-}} = 1.4 \ V$