Select the correct statement regarding the $[Ni(DMG)_2]$ complex compound.

  • A
    It acts as an oxidizing agent because the $Ni^{2+}$ cation has an $EAN$ of $34$.
  • B
    It is extra-stabilized by hydrogen bonding.
  • C
    Its $IUPAC$ name is bis(dimethylglyoximato)nickel$(II)$.
  • D
    Its ligand contains two different donor sites.

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What is the final product formed when copper sulphate solution reacts with excess $KCN$?

Calculate the overall complex dissociation equilibrium constant for the $Cu(NH_3)_4^{2+}$ ion,given that $\beta_4$ for this complex is $2.1 \times 10^{13}$.

Assign $A, B, C, D$ for the given type of reaction: $Fe(CN)_3 \downarrow + 3KCN \longrightarrow K_3[Fe(CN)_6]$

$AgNO_3 \xrightarrow{\Delta} (W) + (X) + O_2$
$(X) + H_2O \longrightarrow HNO_2 + HNO_3$
$(W) + HNO_3 \longrightarrow Y + NO + H_2O$
$(Y) + Na_2S_2O_3(\text{excess}) \longrightarrow (Z) + NaNO_3$
Identify $(W)$ to $(Z)$.

Difficult
View Solution

$Ag^{+} + NH_3 \rightleftharpoons [Ag(NH_3)]^{+}$; $k_1 = 3.5 \times 10^{-3}$
$[Ag(NH_3)]^{+} + NH_3 \rightleftharpoons [Ag(NH_3)_2]^{+}$; $k_2 = 1.7 \times 10^{-3}$
Then the formation constant of $[Ag(NH_3)_2]^{+}$ is

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