The boiling point of water in a $0.1 \ m$ molal silver nitrate solution (solution $A$) is $x \ ^{\circ}C$. To this solution $A$,an equal volume of $0.1 \ m$ molal aqueous barium chloride solution is added to make a new solution $B$. The difference in the boiling points of water in the two solutions $A$ and $B$ is $y \times 10^{-2} \ ^{\circ}C$. (Assume: Densities of the solutions $A$ and $B$ are the same as that of water and the soluble salts dissociate completely. Use: Molal elevation constant,$K_b = 0.5 \ K \ kg \ mol^{-1}$; Boiling point of pure water as $100 \ ^{\circ}C$.) $(1)$ The value of $x$ is $(2)$ The value of $|y|$ is

  • A
    $100.1, 2.50$
  • B
    $101, 2.55$
  • C
    $102, 2.60$
  • D
    $103, 2.66$

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$A$ solution of urea (molar mass $60 \, g \, mol^{-1}$) boils at $100.18 \, ^oC$ at atmospheric pressure. If $K_f$ and $K_b$ for water are $1.86$ and $0.512 \, K \, kg \, mol^{-1}$ respectively,the above solution will freeze at ........... $^oC$.

The osmotic pressure of a $0.5 \ M$ aqueous solution of $CH_3COOH$ having a $pH$ of $2$ at temperature $T$ is . . . . . . . (in $RT$)

What is boiling point? What is freezing point?

Match the following.
$A$. Ebullioscopic constant $I$. Depression of freezing point
$B$. Cryoscopic constant $II$. Total pressure is the sum of partial pressures of the components
$C$. Henry's law $III$. Elevation of boiling point
$D$. Dalton's law $IV$. Solubility of a gas in liquid

The correct match is

Evaluate the following statements for their correctness.
$(A)$ The elevation in boiling point temperature of water will be same for $0.1 \ M \ NaCl$ and $0.1 \ M$ urea.
$(B)$ Azeotropic mixtures boil without change in their composition.
$(C)$ Osmosis always takes place from hypertonic to hypotonic solution.
$(D)$ The density of $32 \% \ H_2SO_4$ solution having molarity $4.09 \ M$ is approximately $1.26 \ g \ mL^{-1}$.
$(E)$ $A$ negatively charged sol is obtained when $KI$ solution is added to silver nitrate solution.
Choose the correct answer from the options given below:

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