$A$ solution of urea (molar mass $60 \, g \, mol^{-1}$) boils at $100.18 \, ^oC$ at atmospheric pressure. If $K_f$ and $K_b$ for water are $1.86$ and $0.512 \, K \, kg \, mol^{-1}$ respectively,the above solution will freeze at ........... $^oC$.

$A$ solution of urea in water has a boiling point of $100.18^{\circ} C$. What is the freezing point of the same solution,if $K_{f}$ and $K_{b}$ of water are $1.86$ and $0.52 \ K \ kg \ mol^{-1}$,respectively (in $^{\circ} C$)? (Boiling point of water $= 100^{\circ} C$ )

An amalgam of mercury with sodium is an example of:

The elevation in boiling point for $1 \ m$ solution of non-volatile solute $A$ is $3 \ K$. The depression in freezing point for $2 \ m$ solution of $A$ in the same solvent is $6 \ K$. The ratio of $K_{b}$ and $K_{f}$ i.e.,$K_{b} / K_{f}$ is $1 : X$. The value of $X$ is [nearest integer].

Given: Molar mass of $C$, $H$, $O$, $Cl$ are $12$, $1$, $16$ and $35.5 \text{ g mol}^{-1}$, respectively. Statement $I$: In $30\%$ (w/w) solution of methanol in $CCl_4$ (at $T \text{ K}$), the mole fraction of $CCl_4$ is equal to $0.33$. Statement $II$: Mixture of methanol and $CCl_4$ shows positive deviation from Raoult's law.

The boiling point of water in a $0.1 \ m$ molal silver nitrate solution (solution $A$) is $x \ ^{\circ}C$. To this solution $A$,an equal volume of $0.1 \ m$ molal aqueous barium chloride solution is added to make a new solution $B$. The difference in the boiling points of water in the two solutions $A$ and $B$ is $y \times 10^{-2} \ ^{\circ}C$. (Assume: Densities of the solutions $A$ and $B$ are the same as that of water and the soluble salts dissociate completely. Use: Molal elevation constant,$K_b = 0.5 \ K \ kg \ mol^{-1}$; Boiling point of pure water as $100 \ ^{\circ}C$.) $(1)$ The value of $x$ is $(2)$ The value of $|y|$ is