The elevation in boiling point for $1 \ m$ solution of non-volatile solute $A$ is $3 \ K$. The depression in freezing point for $2 \ m$ solution of $A$ in the same solvent is $6 \ K$. The ratio of $K_{b}$ and $K_{f}$ i.e.,$K_{b} / K_{f}$ is $1 : X$. The value of $X$ is [nearest integer].

If a $1 \ m$ solution of benzoic acid in benzene has a freezing point depression of $2.56 \ ^{\circ}C$ $(K_f = 5.12 \ ^{\circ}C \ kg \ mol^{-1})$ and a boiling point elevation of $2.53 \ ^{\circ}C$ $(K_b = 2.53 \ ^{\circ}C \ kg \ mol^{-1})$,select the correct statement$(s)$:
Statement $I$: There is dimer formation when undergoing freezing.
Statement $II$: There is no change when undergoing boiling.
Statement $III$: Reverse of $I$ and $II$.
Statement $IV$: Dimer formation in freezing and boiling state.

An aqueous solution freezes at $-0.186\,^\circ C$ ($K_f = 1.86\, K\, kg\, mol^{-1}$; $K_b = 0.512\, K\, kg\, mol^{-1}$). What is the elevation in boiling point?

The ionization constant of a monobasic acid $HA$ is to be determined. If a $0.025 \ m$ aqueous solution of the acid freezes at $-0.060 \ ^{\circ}C$,calculate the ionization constant $K_a$. (Assume molality = molarity and $K_f(H_2O) = 1.86 \ K \ kg \ mol^{-1}$).

An aqueous solution freezes at $-2.55 \ ^oC$. What is its boiling point in $^oC$?
[$K_b(H_2O) = 0.52 \ K \ kg \ mol^{-1}, K_f(H_2O) = 1.86 \ K \ kg \ mol^{-1}$]

The $pH$ of a $0.1 \, M$ monobasic acid is measured to be $2$. Its osmotic pressure at a given temperature $T \, K$ is (in $, RT$)