The enthalpies of formation of gaseous $N_2O$ and $NO$ at $298 \ K$ are $82.0$ and $90.0 \ kJ \ mol^{-1}$ respectively. The enthalpy change of the reaction $N_2O_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow 2 NO_{(g)}$ is

  • A
    $-74 \ kJ$
  • B
    $+98 \ kJ$
  • C
    $+89 \ kJ$
  • D
    $-47 \ kJ$

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Latent heat of vaporisation of a liquid at $500 \ K$ and $1 \ atm$ pressure is $20.0 \ kcal/mol$. What will be the change in internal energy $(\Delta E)$ of $3 \ mol$ of liquid at same temperature in $kcal$?

At constant volume,$5 \, mol$ of a gas shows an increase in temperature by $3.5 \, K$ upon providing $437.5 \, J$ of heat. What will be the molar heat capacity for the gas at constant pressure in $J \, K^{-1} \, mol^{-1}$?

Match List-$I$ with List-$II$. Given $V_1$ and $V_2$ are initial and final volumes respectively.
List-$I$ (Isothermal process) List-$II$ (Expression)
$A$. Reversible expansion $I$. $q = 0$
$B$. Free expansion $II$. $q = nRT \ln \frac{V_2}{V_1}$
$C$. Irreversible Compression $III$. $w = -P_{ext}(V_1 - V_2)$
$D$. Cyclic reversible $IV$. $\frac{q_{rev}}{T} = 0$

The energy of combustion per mole of $H_2$,$LPG$,and octane follows the order:

The entropy change associated with the conversion of $1 \ kg$ of ice at $273 \ K$ to water vapours at $383 \ K$ is: (Specific heat of water liquid and water vapours are $4.2 \ kJ \ K^{-1} \ kg^{-1}$ and $2.0 \ kJ \ K^{-1} \ kg^{-1},$ heat of fusion and vaporisation of water are $334 \ kJ \ kg^{-1}$ and $2491 \ kJ \ kg^{-1},$ respectively) $(\ln \ 273 = 5.61, \ln \ 373 = 5.92, \ln \ 383 = 5.95)$

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