The influence of temperature on the rate of reaction can be found out by

  • A
    Clapeyron-Clausius equation
  • B
    Gibbs-Helmholtz equation
  • C
    Arrhenius equation
  • D
    Van der Waals equation

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Which one of the following does not represent the Arrhenius equation?

Explain: How is the value of activation energy determined based on the Arrhenius equation?

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For reaction $A \to B$,rate constant $K_1 = A_1 e^{-E_{a_1}/RT}$ and for the reaction $X \to Y$,rate constant $K_2 = A_2 e^{-E_{a_2}/RT}$. If $A_1 = 10^8, A_2 = 10^{10}$ and $E_{a_1} = 600 \ cal \ mol^{-1}$,$E_{a_2} = 1800 \ cal \ mol^{-1}$,then the temperature at which $K_1 = K_2$ is (given: $R = 2 \ cal \ K^{-1} \ mol^{-1}$):

Difficult
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The decomposition of formic acid on a gold surface follows first-order kinetics. If the rate constant at $300 \ K$ is $1.0 \times 10^{-3} \ s^{-1}$ and the activation energy $E_a = 11.488 \ kJ \ mol^{-1}$,the rate constant at $200 \ K$ is ............ $\times 10^{-5} \ s^{-1}$.
(Round off to the Nearest Integer).
(Given: $R = 8.314 \ J \ mol^{-1} K^{-1}$)

For a reaction,the activation energy $E_{a} = 0$ and the rate constant at $200 \ K$ is $1.6 \times 10^{6} \ s^{-1}$. The rate constant at $400 \ K$ will be (given $R = 8.314 \ J \ K^{-1} \ mol^{-1}$):

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