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In Column - $I$ the structure of the compound is given,in Column - $II$ the boiling point,and in Column - $III$ the functional group is given. Find the correct match for Column - $I$ from Column - $II$ and Column - $III$.
Column - $I$ (Formula)Column - $II$ (Boiling Point)Column - $III$ (Group)
$(A)$ $CH_3COOH$$(i)$ $309 \ K$$(m)$ Alkane
$(B)$ $CH_3CH_2CH_2OH$$(ii)$ $322 \ K$$(n)$ Ketone
$(C)$ $CH_3COCH_3$$(iii)$ $329 \ K$$(o)$ Aldehyde
$(D)$ $CH_3CH_2CHO$$(iv)$ $391 \ K$$(p)$ Carboxylic acid
$(E)$ $CH_3CH_2CH_2CH_2CH_3$$(v)$ $370 \ K$$(q)$ Alcohol

What is the correct order of increasing acidity for the following compounds?
$I$: Phenol
$II$: Cyclohexanol
$III$: Cyclohexanecarboxylic acid
$IV$: Ethynylcyclohexane

Difficult
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Match List-$I$ and List-$II$.
List-$I$List-$II$
$(a)$ $R-COCl \to R-CHO$$(i)$ $Br_2 / NaOH$
$(b)$ $R-CH_2-COOH \to R-CH(Cl)-COOH$$(ii)$ $H_2 / Pd-BaSO_4$
$(c)$ $R-CONH_2 \to R-NH_2$$(iii)$ $Zn(Hg) / \text{Conc. } HCl$
$(d)$ $R-CO-CH_3 \to R-CH_2-CH_3$$(iv)$ $Cl_2 / \text{Red } P, H_2O$

Choose the correct answer from the options given below:

Give plausible explanation for each of the following:
$(i)$ Cyclohexanone forms cyanohydrin in good yield but $2,2,6-$trimethylcyclohexanone does not.
$(ii)$ There are two $-NH_2$ groups in semicarbazide. However,only one is involved in the formation of semicarbazones.
$(iii)$ During the preparation of esters from a carboxylic acid and an alcohol in the presence of an acid catalyst,the water or the ester should be removed as soon as it is formed.

Difficult
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Arrange the following labelled hydrogens in decreasing order of acidity.

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