The molar heat capacity $(C_p)$ of $CD_2O$ is $10 \, cal \, K^{-1} \, mol^{-1}$ at $1000 \, K$. The change in entropy associated with cooling of $32 \, g$ of $CD_2O$ vapour from $1000 \, K$ to $100 \, K$ at constant pressure will be.....$cal \, deg^{-1}$ ($D = $ deuterium,atomic mass $= 2 \, u$)

The amount of heat evolved when $500 \ cm^{3}$ of $0.1 \ M \ HCl$ is mixed with $200 \ cm^{3}$ of $0.2 \ M \ NaOH$ is (in $kJ$)

Change in entropy for an ideal gas in a reversible isothermal process is given by:

For the complete combustion of methanol
$CH_3OH_{(l)} + \frac{3}{2} O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)}$
the amount of heat produced as measured by a bomb calorimeter is $726 \ kJ \ mol^{-1}$ at $27^{\circ}C$. The enthalpy of combustion for the reaction is $-x \ kJ \ mol^{-1}$,where $x$ is $.....$ (Nearest integer).
(Given: $R = 8.3 \ J \ K^{-1} \ mol^{-1}$)

The enthalpy change for the reaction of $50.00 \ mL$ of ethylene with $50.00 \ mL$ of $H_2$ at $1.5 \ atm$ pressure is $\Delta H = -0.31 \ kJ$. The value of $\Delta E$ will be (in $kJ$)

For the reaction,$2Cl_{(g)} \to Cl_{2(g)}$,the signs of $\Delta H$ and $\Delta S$ respectively,are: