The two substances $A$ and $B$ are in equilibrium with $C$ and $D$ as $2A + B \rightleftharpoons 3C + 2D$. If the initial pressure of $A$ and $B$ are in the ratio of $4:1$ and at equilibrium,the partial pressures of $A$ and $D$ are equal,find the correct relation.

In the reaction $A + 2B \rightleftharpoons 2C$,if $2$ moles of $A$,$3.0$ moles of $B$ and $2.0$ moles of $C$ are placed in a $2.0 \ L$ flask and the equilibrium concentration of $C$ is $0.5 \ mol/L$. The equilibrium constant $K_c$ for the reaction is:

Consider a reaction that is first order in both directions: $A \underset{K_b}{\stackrel{K_f}{\rightleftharpoons}} B$. Initially only $A$ is present,and its concentration is $A_{0}$. Assume $A_{t}$ and $A_{\text{eq}}$ are the concentrations of $A$ at time $t$ and at equilibrium,respectively. The time $t$ at which $A_{t} = (A_{0} + A_{\text{eq}})/2$ is $....$

For the following reactions,equilibrium constants are given:
$S_{(s)} + O_{2(g)} \rightleftharpoons SO_{2(g)}; K_1 = 10^{52}$
$2S_{(s)} + 3O_{2(g)} \rightleftharpoons 2SO_{3(g)}; K_2 = 10^{129}$
The equilibrium constant for the reaction $2SO_{2(g)} + O_{2(g)} \rightleftharpoons 2SO_{3(g)}$ is:

Which one of the following statements is correct for a reversible reaction? $A$ catalyst

Dihydrogen gas is obtained from natural gas by partial oxidation with steam as per the following endothermic reaction:
$CH_{4(g)} + H_2O_{(g)} \rightleftharpoons CO_{(g)} + 3H_{2(g)}$
$(a)$ Write an expression for $K_p$ for the above reaction.
$(b)$ How will the values of $K_p$ and the composition of the equilibrium mixture be affected by:
$(i)$ increasing the pressure
$(ii)$ increasing the temperature
$(iii)$ using a catalyst?