The variation of vapour pressure $(b)$ as a function of temperature $(a)$ is studied for $C_2H_5OC_2H_5$,$CCl_4$,and $H_2O$ at $760 \ mm \ Hg$ and is shown in the figure below. The boiling temperatures of $C_2H_5OC_2H_5$,$CCl_4$,and $H_2O$ are $308 \ K$,$350 \ K$,and $373 \ K$ respectively. Curves $A$,$B$,and $C$ respectively correspond to:

  • A
    $H_2O, C_2H_5OC_2H_5, CCl_4$
  • B
    $C_2H_5OC_2H_5, CCl_4, H_2O$
  • C
    $CCl_4, C_2H_5OC_2H_5, H_2O$
  • D
    $CCl_4, H_2O, C_2H_5OC_2H_5$

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How many grams of a non-volatile solute (molar mass $40 \ g/mol$) must be added to $114 \ g$ of octane to reduce its vapour pressure by $20\%$ (in $g$)?

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