Using molecular orbital theory,compare the bond energy and magnetic character of $O_2^{+}$ and $O_2^{2-}$ species.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) According to molecular orbital theory,the electronic configurations are as follows:
$O_2^{+}: (\sigma 1s)^2 (\sigma^* 1s)^2 (\sigma 2s)^2 (\sigma^* 2s)^2 (\sigma 2p_z)^2 (\pi 2p_x^2, \pi 2p_y^2) (\pi^* 2p_x^1)$
Bond order of $O_2^{+} = \frac{10-5}{2} = 2.5$
$O_2^{2-}: (\sigma 1s)^2 (\sigma^* 1s)^2 (\sigma 2s)^2 (\sigma^* 2s)^2 (\sigma 2p_z)^2 (\pi 2p_x^2, \pi 2p_y^2) (\pi^* 2p_x^2, \pi^* 2p_y^2)$
Bond order of $O_2^{2-} = \frac{10-8}{2} = 1.0$
Since bond energy is directly proportional to bond order,$O_2^{+}$ has higher bond energy than $O_2^{2-}$.
$O_2^{+}$ is paramagnetic due to the presence of one unpaired electron,whereas $O_2^{2-}$ is diamagnetic as all electrons are paired.

Explore More

Similar Questions

Which of the following molecules does not exist on the basis of Molecular Orbital Theory?

How do you express the bond strength in terms of bond order?

In which of the following pairs do the molecules have a bond order of $3$ and are isoelectronic?

Identify the set containing isoelectronic species.

Which of the following molecules has a bond order greater than $1$?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo