Which among the following complexes is homole | vedclass

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(B) complex is homoleptic if the metal atom is bonded to only one type of donor atom/ligand. $A$ complex is cationic if the coordination sphere carrie

Vedclass · Accepted Answer

$\left[Fe(H_{2}O)_{6}\right] Cl_{3}$

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(B) complex is homoleptic if the metal atom is bonded to only one type of donor atom/ligand. $A$ complex is cationic if the coordination sphere carries a positive charge.$1$. $\left[CoCl_{2}(en)_{2}\right] Cl$: Heteroleptic (contains $Cl^-$ and $en$) and cationic.$2$. $\left[Fe(H_{2}O)_{6}\right] Cl_{3}$: Homoleptic (only $H_{2}O$ ligands) and cationic $(\left[Fe(H_{2}O)_{6}\right]^{3+})$.$3$. $K\left[Ag(CN)_{2}\right]$: Homoleptic but anionic $(\left[Ag(CN)_{2}\right]^{-})$.$4$. $\left[Fe(CO)_{5}\right]$: Homoleptic but neutral.Therefore,the correct option is $\left[Fe(H_{2}O)_{6}\right] Cl_{3}$.

Which among the following complexes is homoleptic and cationic in nature?

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