Which chlorine atom is more electronegative i | vedclass

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Question

(D) The electronegativity of an atom in a molecule is influenced by the electron density around it.In these haloalkanes,the alkyl group exerts an indu

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$CH_3-C(CH_3)_2-Cl$

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(D) The electronegativity of an atom in a molecule is influenced by the electron density around it.In these haloalkanes,the alkyl group exerts an inductive effect ($+I$ effect),which increases electron density on the chlorine atom.The order of the $+I$ effect of alkyl groups is: $(CH_3)_3C- > (CH_3)_2CH- > CH_3CH_2- > CH_3-$.As the $+I$ effect increases,the electron density on the chlorine atom increases.Therefore,the chlorine atom in tert-butyl chloride $(CH_3-C(CH_3)_2-Cl)$ experiences the highest electron density due to the strongest $+I$ effect from the tert-butyl group,making it the most electronegative in this series.

Which chlorine atom is more electronegative in the following compounds?

Similar Questions

The major product '$B$' in the below mentioned reaction is:
$CH_3-CH(Br)-CH_3 \xrightarrow[\Delta]{\text{Alc. KOH}} A \xrightarrow[\text{Peroxide absent}]{\text{HBr}} B$

Write a note on $S_{N}2$ mechanism.

What do you mean by dehydrohalogenation?

Arrange the following compounds in order of decreasing rate of hydrolysis for $S_N1$ reaction:
$(i)$ $C_6H_5CH_2Br$
(ii) $p-CH_3-C_6H_4-CH_2Br$
(iii) $p-CH_3CH_2-C_6H_4-CH_2Br$
(iv) $p-(CH_3)_2CH-C_6H_4-CH_2Br$

The reactivity of $2-$bromo$-2-$methylbutane $(I)$,$1-$bromopentane $(II)$ and $2-$bromopentane $(III)$ towards $S_N2$ displacement is such that :

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