Which of the following is amphoteric?

The amphoteric oxide of Vanadium $(V)$ is $V_2O_5$. It reacts with alkali to form an oxoion '$X$' and with acid to form an oxoion '$Y$'. The oxidation states of '$V$' in '$X$' and '$Y$' are respectively:

Boiling $CuCl_2$ with $Cu$ in concentrated $HCl$ gives:

In the scheme given below,$X$ and $Y$,respectively,are:
$\text{Metal halide} \xrightarrow{\text{aq. NaOH}} \text{White precipitate } (P) + \text{Filtrate } (Q)$
$P \xrightarrow[\text{heat}]{\text{aq. } H_2SO_4, PbO_2 (\text{excess})} X (\text{a coloured species in solution})$
$Q$ $\xrightarrow[\text{warm}]{\text{MnO(OH)}_2, \text{Conc. } H_2SO_4} Y (\text{gives blue-coloration with KI-starch paper})$

$A$ purple colored compound of Manganese $(X)$ decomposes on heating to liberate oxygen and forms compounds of Manganese $(Y)$ and $(Z)$. Compound $(Z)$ reacts with $KOH$ in the presence of potassium nitrate to give compound $(Y)$. Compounds $(X)$,$(Y)$,and $(Z)$ respectively are:

On heating a mixture of common salt and $K_{2}Cr_{2}O_{7}$ with concentrated $H_{2}SO_{4}$, a gas is evolved. The formula of the gas evolved and the oxidation state of the central metal atom in the gas, respectively, are: