Which of the following complexes possesses a meridional $(mer)$ isomer?

  • A
    $[Co(NH_3)_3Cl_3]$
  • B
    $[Co(NH_3)_4Cl_2]$
  • C
    $[Co(NH_3)_2Cl_4]$
  • D
    $[Co(NH_3)_5Cl]$

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The correct match for the complex with its magnetic behavior is:

$A$ chromium complex with a formula $CrCl_3 \cdot 6H_2O$ has a spin-only magnetic moment value of $3.87 \ BM$ and its solution conductivity corresponds to a $1:2$ electrolyte. $2.75 \ g$ of the complex was dissolved and passed through a cation exchanger. The solution obtained after the process was reacted with excess $AgNO_3$. The amount of $AgCl$ formed in the above process is . . . . . . $g$. (Nearest integer) [Given: Molar mass in $g \ mol^{-1}$: $Cr = 52, Cl = 35.5, Ag = 108, O = 16, H = 1$]

How can the isomeric complexes $[Co(NH_3)_6][Cr(NO_2)_6]$ and $[Cr(NH_3)_6][Co(NO_2)_6]$ be distinguished from one another?

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For the correct assignment of electronic configuration of a complex,the valence bond theory often requires the measurement of

The $[Cr(NH_3)_6]^{3+}$ ion is ...

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