Which of the following compounds has the most difficulty in breaking the $C-Cl$ bond?

How many reactions of aryl halides with metals are there? Explain with examples.

Rank the following compounds in order of decreasing rate of reaction with alkoxide ion $(CH_3CH_2O^{-})$ in a nucleophilic aromatic substitution reaction:
$1$. $1$-bromo-$2$-nitrobenzene
$2$. $1$-bromo-$3$-nitrobenzene
$3$. $1$-bromo-$2,4$-dinitrobenzene
$4$. $1$-bromo-$3,4$-dinitrobenzene

With respect to chlorobenzene,which of the following statements is not correct?

Identify the major product of the following reaction: $C_6H_5Cl + Br_2 \xrightarrow{\text{Anhyd. } FeCl_3} ?$

The reaction of compound $P$ with $CH_3MgBr$ (excess) in $(C_2H_5)_2O$ followed by addition of $H_2O$ gives $Q$. The compound $Q$ on treatment with $H_2SO_4$ at $0^{\circ}C$ gives $R$. The reaction of $R$ with $CH_3COCl$ in the presence of anhydrous $AlCl_3$ in $CH_2Cl_2$ followed by treatment with $H_2O$ produces compound $S$ [$Et$ in compound $P$ is ethyl group].
$(1)$ The product $S$ is
$(2)$ The reactions,$Q$ to $R$ and $R$ to $S$,are

$A$. Dehydration and Friedel-Crafts acylation	$B$. Aromatic sulfonation and Friedel-Crafts acylation
$C$. Friedel-Crafts alkylation,dehydration and Friedel-Crafts acylation	$D$. Friedel-Crafts alkylation and Friedel-Crafts acylation

Given the answer question $(1)$ and $(2)$