Which of the following equations relates the temperature of a reaction with $\Delta H^{\circ}$ and $\Delta S^{\circ}$ at equilibrium?

  • A
    $\Delta H^{\circ} = \frac{T}{\Delta S^{\circ}}$
  • B
    $\Delta H^{\circ} = \frac{\Delta S^{\circ}}{T}$
  • C
    $\Delta H^{\circ} = T \Delta S^{\circ}$
  • D
    $\Delta H^{\circ} = \frac{1}{T \Delta S^{\circ}}$

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At $298 \ K$,for the reaction $N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$,the $K_p$ value is $0.98$. Predict whether the reaction is spontaneous or not.

Consider the reaction $X \rightleftharpoons Y$ at $300 \text{ K}$. If $\Delta H^\circ$ and $K$ are $28.40 \text{ kJ mol}^{-1}$ and $1.8 \times 10^{-7}$ at the same temperature, then the magnitude of $\Delta S^\circ$ for the reaction in $\text{J K}^{-1} \text{ mol}^{-1}$ is . . . . . . . (Nearest integer) (Given: $R = 8.3 \text{ J K}^{-1} \text{ mol}^{-1}$, $\ln 10 = 2.3$, $\log 3 = 0.48$, $\log 2 = 0.30$)

Given $\Delta G^o (HI, g) \cong + 1.7 \ kJ \ mol^{-1}$. What is the equilibrium constant at $25 ^oC$ for the reaction $2HI_{(g)} \rightleftharpoons H_{2_{(g)}} + I_{2_{(g)}}$?

Assertion: For every chemical reaction at equilibrium,the standard Gibbs energy change is zero.
Reason: At constant temperature and pressure,a chemical reaction is spontaneous in the direction of decreasing Gibbs energy.

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