Which of the following formulae is used to calculate the depression in freezing point?

Ethylene glycol is used as an antifreeze in cold climates. The mass of ethylene glycol $(C_2H_6O_2)$ that should be added to $4 \ kg$ of water to prevent it from freezing at $-6 \ ^oC$ is ......... $g$.
($K_f$ for water $= 1.86 \ K \ kg \ mol^{-1}$,and molar mass of ethylene glycol $= 62 \ g \ mol^{-1}$)

The freezing point of a solution containing $4.8 \ g$ of a compound in $60 \ g$ of benzene is $4.48 ^\circ C$. What is the molar mass of the compound $(K_f = 5.1 \ K \ kg \ mol^{-1})$,(freezing point of benzene $= 5.5 ^\circ C$)?

Which of the following $0.10 \ m$ aqueous solutions will have the lowest freezing point?

Calculate the cryoscopic constant $(K_f)$ of a solvent if the depression in freezing point of a $0.3 \text{ m}$ solution of a nonelectrolyte is $0.48 \text{ K}$.

The freezing point of a $0.01 \ M$ aqueous glucose solution at $1 \ \text{atmosphere}$ is $-0.18 \ ^oC$. To it,an addition of an equal volume of $0.002 \ M$ glucose solution will produce a solution with a freezing point of nearly ........... $^oC$.