Which of the following processes exhibits an increase in internal energy?

In a cylinder,$1.0 \, \text{kcal}$ of heat is added to $1.2 \, \text{L}$ of $O_2$ gas at a constant pressure of $1 \, \text{atm}$. The volume changes to $1.5 \, \text{L}$. Calculate the change in internal energy $(\Delta U)$ for this process. (in $, \text{kcal}$)

In a $1 \, L$ container,$2 \, mol$ of $CO$ and $1 \, mol$ of $O_2$ are taken. They react according to the equation: $2CO(g) + O_2(g) \rightarrow 2CO_2(g)$,$\Delta H = -560 \, kJ$. Given that $1 \, atm \cdot L = 0.1 \, kJ$,and the pressure changes from $70 \, atm$ to $40 \, atm$ at $500 \, K$,calculate the value of $\Delta U$ in $kJ$.

For the reaction $PCl_{5(g)} \to PCl_{3(g)} + Cl_{2(g)}$,which of the following relations is correct?

$4.0 \, L$ of an ideal gas is allowed to expand isothermally into vacuum until the total volume is $20 \, L$. The amount of heat absorbed in this expansion is $..... \, L \, atm$.

For the reaction $N_2(g) + 3H_2(g) \rightarrow 2NH_3(g)$ at constant temperature and pressure,if $\Delta H$ and $\Delta U$ are the enthalpy and internal energy changes for the reaction,which of the following equations is correct?