Which of the two: $O_2NCH_2CH_2O^{-}$ or $CH_3CH_2O^{-}$ is expected to be more stable and why?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) $NO_2$ group is an electron-withdrawing group. Hence,it shows $-I$ effect.
By withdrawing the electrons toward it,the $NO_2$ group decreases the negative charge on the compound,thereby stabilising it.
On the other hand,the ethyl group $(CH_3CH_2-)$ is an electron-releasing group. Hence,the ethyl group shows $+I$ effect.
This increases the negative charge on the compound,thereby destabilising it.
Hence,$O_2NCH_2CH_2O^{-}$ is expected to be more stable than $CH_3CH_2O^{-}$.

Explore More

Similar Questions

The electromeric effect in organic compounds is a....

Which of the following is an incorrect representation of the electromeric effect?

The correct order of stability for the following alkoxides is:
$(A)$ $CH_3CH(NO_2)O^-$
$(B)$ $CH_2=C(NO_2)O^-$
$(C)$ $O_2N-CH=CH-O^-$

Which of the following structures possesses a cross-conjugated system?

Which of the following statements are correct?
$(i)$ Inductive effect and resonance effect are possible in chlorobenzene.
$(ii)$ Resonance effect dominates over inductive effect in anisole.
$(iii)$ $p-$nitrobenzoic acid is less acidic than $m-$nitrobenzoic acid.
$(iv)$ Diphenylamine is more basic than aniline.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo