(D) Reduction of nitro compounds ($R-NO_2$ or $Ar-NO_2$) yields primary amines ($R-NH_2$ or $Ar-NH_2$).Reduction of nitriles $(R-CN)$ yields primary a

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(D) Reduction of nitro compounds ($R-NO_2$ or $Ar-NO_2$) yields primary amines ($R-NH_2$ or $Ar-NH_2$).Reduction of nitriles $(R-CN)$ yields primary amines $(R-CH_2NH_2)$.Reduction of isonitriles $(R-NC)$ yields secondary amines $(R-NH-CH_3)$.Therefore,$R-NC$ does not give a primary amine upon reduction.