Which one of the following is an incorrect statement for physisorption?

When a graph is plotted between $\log (x/m)$ and $\log P$,it is a straight line with an angle of $45^o$ and an intercept of $0.3010$ on the $y-$axis. If the initial pressure is $0.3 \ atm$,what will be the amount of gas adsorbed per $g$ of adsorbent $(x/m)$?

The Langmuir adsorption isotherm is deduced using the assumption that:

$CO_{2}$ gas adsorbs on charcoal following Freundlich adsorption isotherm. For a given amount of charcoal,the mass of $CO_{2}$ adsorbed becomes $64$ times when the pressure of $CO_{2}$ is doubled. The value of $n$ in the Freundlich isotherm equation is $......\,\times 10^{-2}$. (Round off to the Nearest Integer)

Which of the following statements is incorrect regarding physical adsorption?

$A$ particular adsorption process has the following characteristics: $(i)$ It arises due to van der Waals forces and $(ii)$ it is reversible. Identify the correct statement that describes the above adsorption process.