Which one of the following is not a buffer solution?

  • A
    $0.8 \ M \ H_2S + 0.8 \ M \ KHS$
  • B
    $2 \ M \ C_6H_5NH_2 + 2 \ M \ C_6H_5NH_3Br$
  • C
    $3 \ M \ H_2CO_3 + 3 \ M \ KHCO_3$
  • D
    $0.05 \ M \ KClO_4 + 0.05 \ M \ HClO_4$

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When an acid or alkali is mixed with a buffer solution,the $pH$ of the buffer solution:

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