Which one of the following non-ideal solutions shows negative deviation?

Given:
Solution $A$: Phenol and aniline
Solution $B$: Chloroform and acetone
Which of the following is correct as per Raoult's law?

Liquids $A$ and $B$ form an ideal solution. The vapour pressure of pure $A$ and $B$ are $50 \ mm \ Hg$ and $32 \ mm \ Hg$ respectively at $300 \ K$. One mole of liquid $A$ is mixed with $1$ mole of liquid $B$. What is the approximate mole fraction of $A$ in the vapour phase?

Which of the following pairs does not form an ideal solution?

Two liquids $A$ and $B$ form an ideal solution. When they are mixed in a molar ratio of $1:1$,the vapor pressure of the solution at $300 \ K$ is $400 \ mm \ Hg$. When they are mixed in a molar ratio of $1:2$,the vapor pressure of the solution at the same temperature is $350 \ mm \ Hg$. The vapor pressures of pure liquids $A$ and $B$ are respectively:

Which of the following mixture$(s)$ show$(s)$ positive deviation from Raoult's law at $35^{\circ}C$?
$(A)$ Carbon tetrachloride + methanol
$(B)$ Carbon disulphide + acetone
$(C)$ Benzene + toluene
$(D)$ Phenol + aniline