Which one of the following will increase the voltage of the cell? $(T = 298 \ K)$ :- $Sn_{(s)} + 2Ag_{(aq)}^{+} \rightarrow Sn_{(aq)}^{2+} + 2Ag_{(s)}$

  • A
    Decrease in the concentration of $Ag^{+}$ ions
  • B
    Increase in the concentration of $Sn^{2+}$ ions
  • C
    Increase in the concentration of $Ag^{+}$ ions
  • D
    None of the above

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$Cu_{(s)} + Sn^{2+}(0.001 \ M) \rightarrow Cu^{2+}(0.01 \ M) + Sn_{(s)}$
The Gibbs free energy change for the above reaction at $298 \ K$ is $x \times 10^{-1} \ kJ \ mol^{-1}$;
The value of $x$ is ..... [nearest integer] $\left[\text{Given}: E^{\ominus}_{Cu^{2+}/Cu} = 0.34 \ V; E^{\ominus}_{Sn^{2+}/Sn} = -0.14 \ V; F = 96500 \ C \ mol^{-1}\right]$

For a half-cell containing a $Pt$ rod immersed in a solution of $1 \ M$ $HA$,$O_{2(g)}$ is bubbled at $1 \ atm$. The standard reduction potential for water formation is $1.23 \ V$. Given a dissociation constant,$K_a = 1 \times 10^{-4}$ for $HA$,what is $E_{\text{Half-cell}}$ at $298 \ K$ in $V$?

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