Which reagent can be used to identify nickel ion $(Ni^{2+})$?

Three different samples of a salt solution give the following test results: One sample gives a white precipitate with ammonia solution. One sample gives a white precipitate with dilute $NaCl$ solution. One sample gives a black precipitate with $H_2S$. Identify the salt.

When $H_2S$ gas is passed through a hot acidic aqueous solution containing $Al^{3+}$,$Cu^{2+}$,$Pb^{2+}$ and $Ni^{2+}$,a precipitate is formed,which consists of

Match List-$I$ with List-$II$:

List-$I$ (Ion)	List-$II$ (Group Number in Cation Analysis)
$A. Co^{2+}$	$I. Group-I$
$B. Mg^{2+}$	$II. Group-III$
$C. Pb^{2+}$	$III. Group-IV$
$D. Al^{3+}$	$IV. Group-VI$

Choose the correct answer from the options given below:

The qualitative distinction of $ZnSO_4$ and $Al_2(SO_4)_3$ can be done by using the reagent

Passing $H_2S$ gas into a mixture of $Mn^{2+}$,$Ni^{2+}$,$Cu^{2+}$ and $Hg^{2+}$ ions in an acidified aqueous solution precipitates