Which will have minimum osmotic pressure?

If $5\%$ sugar solution is isotonic with $1\%$ solution of unknown substance,then find out the molecular mass of the unknown substance. (in $g/mol$)

The osmotic pressure of sea water is $1.05 \ atm$. Four experiments were carried out as shown in the table below. In which of the following experiments can pure water be obtained in part-$II$ of the vessel?
| Experiment | Pressure applied on part-$I$ $(atm)$ | Pressure applied on part-$II$ $(atm)$ |
| :--- | :--- | :--- |
| $I$ | $2.0$ | $1.0$ |
| $II$ | $1.0$ | $2.0$ |
| $III$ | $3.0$ | $1.0$ |
| $IV$ | $1.0$ | $1.0$ |

Osmotic pressure of $0.1 \ M$ aqueous solution of $MgCl_2$ at $300 \ K$ is $4.92 \ atm$. What will be the percentage ionization of the salt? $.......... \ \%$

$A$ solution of $12 \ g$ of non-electrolyte $(A)$ prepared by dissolving it in $1000 \ mL$ of water exerts the same osmotic pressure as that of a $0.05 \ M$ glucose solution at the same temperature. The empirical formula of $A$ is $CH_2O$. The molecular mass of $A$ is $.......... \ g \ mol^{-1}$. (Nearest integer)

What is the osmotic pressure of a solution prepared by dissolving $3 \ g$ of solute in $2 \ dm^3$ of water at $300 \ K$ (in $atm$)? (Molar mass of solute $= 60 \ g \ mol^{-1}$,$R = 0.0821 \ dm^3 \ atm \ K^{-1} \ mol^{-1}$)