Write the balanced chemical equation for the following reaction in an acidic medium using the ion-electron method:
Permanganate ion $(MnO_4^-)$ reacts with sulphur dioxide gas to produce $Mn^{+2}$ and hydrogen sulphate ion $(HSO_4^-)$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The unbalanced equation is:
$MnO_{4_{(aq)}}^{-} + SO_{2_{(g)}} \rightarrow Mn_{(aq)}^{+2} + HSO_{4_{(aq)}}^{-}$
Step $1$: Separate into two half-reactions:
Reduction Half-Reaction $(R.H.R.)$ : $MnO_{4_{(aq)}}^{-} \rightarrow Mn_{(aq)}^{+2}$
Oxidation Half-Reaction $(O.H.R.)$ : $SO_{2_{(g)}} \rightarrow HSO_{4_{(aq)}}^{-}$
Step $2$: Balance atoms and charges in each half-reaction in acidic medium:
$R.H.R.$ : $MnO_{4_{(aq)}}^{-} + 8H_{(aq)}^{+} + 5e^{-} \rightarrow Mn_{(aq)}^{+2} + 4H_{2}O_{(l)}$
$O.H.R.$ : $SO_{2_{(g)}} + 2H_{2}O_{(l)} \rightarrow HSO_{4_{(aq)}}^{-} + 3H_{(aq)}^{+} + 2e^{-}$
Step $3$: Equalize the number of electrons by multiplying $R.H.R.$ by $2$ and $O.H.R.$ by $5$:
$2MnO_{4_{(aq)}}^{-} + 16H_{(aq)}^{+} + 10e^{-} \rightarrow 2Mn_{(aq)}^{+2} + 8H_{2}O_{(l)}$
$5SO_{2_{(g)}} + 10H_{2}O_{(l)} \rightarrow 5HSO_{4_{(aq)}}^{-} + 15H_{(aq)}^{+} + 10e^{-}$
Step $4$: Add the two half-reactions:
$2MnO_{4_{(aq)}}^{-} + 5SO_{2_{(g)}} + 16H_{(aq)}^{+} + 10H_{2}O_{(l)}$ $\rightarrow 2Mn_{(aq)}^{+2} + 5HSO_{4_{(aq)}}^{-} + 15H_{(aq)}^{+} + 8H_{2}O_{(l)}$
Simplifying the equation:
$2MnO_{4_{(aq)}}^{-} + 5SO_{2_{(g)}} + 2H_{2}O_{(l)} + H_{(aq)}^{+} \rightarrow 2Mn_{(aq)}^{+2} + 5HSO_{4_{(aq)}}^{-}$

Explore More

Similar Questions

Which of the following is a redox reaction?
$(i) \, CdCl_2 + 2 KOH \longrightarrow Cd(OH)_2 + 2 KCl$
$(ii) \, BaCl_2 + K_2SO_4 \longrightarrow BaSO_4 + 2 KCl$
$(iii) \, CaCO_3 \longrightarrow CaO + CO_2$
$(iv) \, 2 Ca + O_2 \longrightarrow 2 CaO$

What is the number of electrons gained by $Cl$ atom when $n$ mole of $ClO_4^-$ is transformed into $n$ mole of $ClO_2^-$ ion?

Justify that the reaction: $2 Na ( s ) + H_2 ( g ) \rightarrow 2 NaH ( s )$ is a redox change.

Assign $A, B, C, D$ from the given type of reaction.
$2NaI + 2H_2SO_4 \,(Conc.) \longrightarrow Na_2SO_4 + I_2 + SO_2 + 2H_2O$

Manganese ions $(Mn^{2+})$ can be oxidised by persulphate ions $(S_2O_8^{2-})$ according to the following half-equations:
$S_2O_8^{2-} + 2e^- \longrightarrow 2SO_4^{2-}$
$Mn^{2+} + 4H_2O \longrightarrow MnO_4^- + 8H^+ + 5e^-$
How many moles of $S_2O_8^{2-}$ are required to oxidise $1 \ mole$ of $Mn^{2+}$?

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo