For the reaction $X_{(g)} + Y_{(g)} \rightleftharpoons Z_{(g)}$ at $550 \ K$,the value of $K_c$ is $10^{-4} \ mol^{-1} \ L$. If at equilibrium $[X] = \frac{1}{2}[Y] = \frac{1}{2}[Z]$,then the value of $[Z]$ at equilibrium will be:

  • A
    $2 \times 10^{-4} \ M$
  • B
    $1 \times 10^{-4} \ M$
  • C
    $2 \times 10^{4} \ M$
  • D
    $1 \times 10^{4} \ M$

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The equilibrium constant at $298 \ K$ for a reaction $A + B \rightleftharpoons C + D$ is $100$. If the initial concentration of all the four species were $1 \ M$ each,then the equilibrium concentration of $D$ (in $mol \ L^{-1}$) will be:

Consider the reaction,$P(aq) \rightleftharpoons Q(aq)$ with an equilibrium constant $K=1.5$. The reaction is started in a vessel with a concentration of $[P]$ of $2 \ M$ and concentration of $[Q]=0$. When the equilibrium is established,half the amount of $P$ is removed,and the reaction is allowed to re-equilibrate. The concentration of $Q$ in the vessel (in $M$) is closest to

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