For which of the following thermodynamic processes is $\Delta U = 0$?

Which of the following statements or relationships is not correct in thermodynamic changes?

Match the following:

List-$I$	List-$II$
$(A) \Delta U = W_{ad}$	$I.$ Isothermal reversible expansion
$(B) \Delta U = q - W$	$II.$ Wall is adiabatic
$(C) \Delta U = -q$	$III.$ Thermally conducting walls
$(D) \Delta U = 0$	$IV.$ Isolated system
	$V.$ Closed system

The correct answer is

$10 \, mol$ of an ideal gas expands isothermally and reversibly from a pressure of $10 \, atm$ to $1 \, atm$ at $300 \, K$. What is the largest mass (in $kg$) which can be lifted through a height of $100 \, m$ by the energy obtained in this process (in $, kg$)?

Given
$C_{(graphite)} + O_{2(g)} \rightarrow CO_{2(g)};$
$\Delta_rH^o = -393.5 \, kJ \, mol^{-1}$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_2O_{(l)};$
$\Delta_rH^o = -285.8 \, kJ \, mol^{-1}$
$CO_{2(g)} + 2H_2O_{(l)} \rightarrow CH_{4(g)} + 2O_{2(g)};$
$\Delta_rH^o = + 890.3 \, kJ \, mol^{-1}$
Based on the above thermochemical equations,the value of $\Delta_rH^o$ at $298 \, K$ for the reaction
$C_{(graphite)} + 2H_{2(g)} \rightarrow CH_{4(g)}$ will be ........... $kJ \, mol^{-1}$.

$A$ gas (Molar mass $= 280 \ g \ mol^{-1}$) was burnt in excess $O_2$ in a constant volume calorimeter and during combustion the temperature of calorimeter increased from $298.0 \ K$ to $298.45 \ K$. If the heat capacity of calorimeter is $2.5 \ kJ \ K^{-1}$ and enthalpy of combustion of gas is $9 \ kJ \ mol^{-1}$,then the amount of gas burnt is $...... \ g$. (Nearest Integer)