Discuss the complex species $[Co(NH_3)_6]^{3+}$ based on Valence Bond Theory.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $1$. The central metal ion $Co^{3+}$ has an electronic configuration of $[Ar]3d^6$.
$2$. In the presence of the strong field ligand $NH_3$,the electrons in the $3d$ orbitals pair up,leaving two $3d$ orbitals vacant.
$3$. These two $3d$ orbitals,along with one $4s$ and three $4p$ orbitals,undergo $d^2sp^3$ hybridization to form six equivalent hybrid orbitals.
$4$. Six pairs of electrons from six $NH_3$ ligands occupy these hybrid orbitals,resulting in an octahedral geometry.
$5$. Since there are no unpaired electrons,the complex is diamagnetic.
$6$. Because the inner $3d$ orbitals are involved in hybridization,it is called an inner orbital complex or a low-spin complex.

Explore More

Similar Questions

Assertion $:$ Complex ion $[Co(NH_3)_6]^{2+}$ is readily oxidized to $[Co(NH_3)_6]^{3+}$.
Reason $:$ Unpaired electron in complex ion $[Co(NH_3)_6]^{2+}$ is present in $4p$ orbital.

$[Cu(NH_3)_4]^{2+}$ has hybridisation and magnetic moment

The correct order of hybridization of the central atom in the following species $NH_3$,$[PtCl_4]^{2-}$,$PCl_5$,and $BCl_3$ is

Given below are two statements:
Statement $I$: $[Mn(CN)_6]^{3-}$,$[Fe(CN)_6]^{3-}$ and $[Co(C_2O_4)_3]^{3-}$ are $d^2sp^3$ hybridized.
Statement $II$: $[MnCl_6]^{3-}$ and $[FeF_6]^{3-}$ are paramagnetic and have $4$ and $5$ unpaired electrons,respectively.
In the light of the above statements,choose the correct answer from the options given below:

Discuss the $[NiCl_4]^{2-}$ complex species based on Valence Bond Theory.

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo