$37.8 \ g$ $N_2O_5$ was taken in a $1 \ L$ reaction vessel and allowed to undergo the following reaction at $500 \ K$:
$2N_2O_{5(g)} \rightarrow 2N_2O_{4(g)} + O_{2(g)}$
The total pressure at equilibrium was found to be $18.65 \ bar$. Then,$K_p = \text{ . . . . . . } \times 10^{-2}$ [nearest integer].
Assume $N_2O_5$ to behave ideally under these conditions.
Given: $R = 0.082 \ bar \ L \ mol^{-1} \ K^{-1}$

For which of the following reactions will $K_p < K_c$?

When $20 \ g$ of $CaCO_3$ are subjected to decomposition at $227 \ ^oC$ in a closed container of $10 \ L$ capacity,$50 \%$ of $CaCO_3$ remained unreacted at equilibrium. Calculate $K_P$ for $CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$ in $atm$.

At a certain temperature,the equilibrium constant $K_c$ is $0.25$ for the reaction:
$A_{2(g)} + B_{2(g)} \rightleftharpoons C_{2(g)} + D_{2(g)}$
If we take $1 \ mol$ of each of the four gases in a $10 \ L$ container,what would be the equilibrium concentration of $A_{2(g)}$ (in $M$)?

For a reaction,$A \rightleftharpoons P$,the plots of $[A]$ and $[P]$ with time at temperatures $T_1$ and $T_2$ are given below. If $T_2 > T_1$,the correct statement$(s)$ is (are) (Assume $\Delta H^{\ominus}$ and $\Delta S^{\ominus}$ are independent of temperature and ratio of $\ln K$ at $T_1$ to $\ln K$ at $T_2$ is greater than $T_2 / T_1$. Here $H, S, G$ and $K$ are enthalpy,entropy,Gibbs energy and equilibrium constant,respectively.)
$(A)$ $\Delta H^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(B)$ $\Delta G^{\ominus} < 0, \Delta H^{\ominus} > 0$
$(C)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(D)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} > 0$

For the reaction $X(s) \rightleftharpoons Y(s) + Z(g)$,the plot of $\ln \frac{p_z}{p^\ominus}$ versus $\frac{10^4}{T}$ is given below,where $p_z$ is the pressure (in bar) of the gas $Z$ at temperature $T$ and $p^\ominus = 1 \ bar$.
(Given,$\frac{d(\ln K)}{d(\frac{1}{T})} = -\frac{\Delta H^\ominus}{R}$,where the equilibrium constant,$K = \frac{p_z}{p^\ominus}$ and the gas constant,$R = 8.314 \ J \ K^{-1} \ mol^{-1}$)
$(1)$ The value of standard enthalpy,$\Delta H^\ominus$ (in $kJ \ mol^{-1}$) for the reaction is. . . . . . .
$(2)$ The value of $\Delta S^\ominus$ (in $J \ K^{-1} \ mol^{-1}$) for the given reaction,at $1000 \ K$ is. . . . . .
Give the answer for $(1)$ and $(2)$