$0.001 \ mol$ of $Co(NH_3)_5(NO_3)(SO_4)$ was passed through a cation exchanger. The acid coming out of it required $20 \ mL$ of $0.1 \ M$ $NaOH$ for neutralization. Hence,the complex is:

  • A
    $[Co(NH_3)_5SO_4]NO_3$
  • B
    $[Co(NH_3)_5NO_3]SO_4$
  • C
    $[Co(NH_3)_5](SO_4)(NO_3)$
  • D
    none of these

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Which of the following has a yellow colour?

Choose the correct statement$(s)$ among the following:
$(A)$ $[FeCl_4]^-$ has tetrahedral geometry.
$(B)$ $[Co(en)(NH_3)_2Cl_2]^+$ has $2$ geometrical isomers.
$(C)$ $[FeCl_4]^-$ has higher spin-only magnetic moment than $[Co(en)(NH_3)_2Cl_2]^+$.
$(D)$ The cobalt ion in $[Co(en)(NH_3)_2Cl_2]^+$ has $sp^3d^2$ hybridization.

Given below are two statements:
Statement $I$: $PF_5$ and $BrF_5$ both exhibit $sp^3 d$ hybridisation.
Statement $II$: Both $SF_6$ and $[Co(NH_3)_6]^{3+}$ exhibit $sp^3 d^2$ hybridisation.
In the light of the above statements,choose the correct answer from the options given below:

The complexes given below show:

$A$ mixture $X$ containing $0.02 \, mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \, mol$ of $[Co(NH_3)_5Br]SO_4$ is dissolved in water to make a $2 \, L$ solution.
$1 \, L \, of \, X + \text{Excess of } AgNO_3 \rightarrow Y \, mol \, of \, ppt.$
$1 \, L \, of \, X + \text{Excess of } BaCl_2 \rightarrow Z \, mol \, of \, ppt.$
Then $Y$ and $Z$ are respectively ...............

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