Assertion : $RCOCl$,$(RCO)_2O$ and $RCOOR'$ all react with Grignard reagents to form $3^o$ alcohols.
Reason : $RCOCl$ reacts with $R_2Cd$ to form ketones but $(RCO)_2O$ and $RCOOR'$ do not react at all.

Match the reactions given in Column-$I$ with the appropriate reagents in Column-$II$.
| Column-$I$ (Reaction) | Column-$II$ (Reagent) |
| :--- | :--- |
| $(A)$ $2CH_3COOH \rightarrow (CH_3CO)_2O$ | $(i)$ $(I) NH_3, (II) \Delta, -H_2O$ |
| $(B)$ Phthalic acid $\rightarrow$ Phthalamide | $(ii)$ $(I) Br_2 / \text{red phosphorous}, (II) H_2O$ |
| $(C)$ $CH_3CH_2COOH \rightarrow CH_3CHBrCOOH$ | $(iii)$ $Br_2 / FeBr_3$ |
| $(D)$ Benzoic acid $\rightarrow$ $m$-Bromobenzoic acid | $(iv)$ $H^+, \Delta \text{ OR } P_2O_5, \Delta$ |

Arrange the following compounds in increasing order of their property as indicated:
$(i)$ Acetaldehyde,Acetone,Di-tert-butyl ketone,Methyl tert-butyl ketone (reactivity towards $HCN$)
$(ii)$ $CH_3CH_2CH(Br)COOH$,$CH_3CH(Br)CH_2COOH$,$(CH_3)_2CHCOOH$,$CH_3CH_2CH_2COOH$ (acid strength)
$(iii)$ Benzoic acid,$4$-Nitrobenzoic acid,$3,4$-Dinitrobenzoic acid,$4$-Methoxybenzoic acid (acid strength)

Which $\beta$-keto acid shown will not undergo decarboxylation?

Match List-$I$ with List-$II$.
List-$I$:
$(a)$ $\text{Benzene} \xrightarrow[\text{CuCl}]{\text{CO, HCl, Anhyd. AlCl}_3} \text{Benzaldehyde}$
$(b)$ $R-CO-CH_3 + NaOX \rightarrow$
$(c)$ $R-CH_2-OH + R'COOH \xrightarrow{\text{Conc. H}_2\text{SO}_4}$
$(d)$ $R-CH_2COOH \xrightarrow[(ii) H_2O]{(i) X_2/\text{Red P}} R-CH(X)COOH$
List-$II$:
$(i)$ $\text{Hell-Volhard-Zelinsky reaction}$
(ii) $\text{Gattermann-Koch reaction}$
(iii) $\text{Haloform reaction}$
(iv) $\text{Esterification}$
Choose the correct answer from the options given below.

The reaction sequence is:
$2-\text{hydroxycyclohexylacetone}$ $\xrightarrow{I_2/NaOH}$ $\xrightarrow{\Delta}$ $\xrightarrow{H^+}$ $\xrightarrow{\Delta} A$
$A$ is: