At $T \ K$,$K_{c}$ for the reaction $SO_{2(g)} + NO_{2(g)} \rightleftharpoons SO_{3(g)} + NO_{(g)}$ is $16$. If initially one mole each of all the four gases are taken in a $1 \ L$ vessel,the equilibrium concentrations of $SO_{3(g)}$ and $SO_{2(g)}$ in $mol \ L^{-1}$ respectively are:

For the reaction $N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)}$,the equilibrium constant is $K_1$. For the reaction $2NO_{(g)} + O_{2(g)} \rightleftharpoons 2NO_{2(g)}$,the equilibrium constant is $K_2$. The equilibrium constant $K$ for the reaction $NO_{2(g)} \rightleftharpoons \frac{1}{2}N_{2(g)} + O_{2(g)}$ will be:

$N_2O_{4(g)}$ at $300 \ K$ is kept in a closed container under $1 \ atm$. At equilibrium,$20\%$ of $N_2O_{4(g)}$ is converted to $NO_{2(g)}$.
$N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$
Hence,the resultant pressure is: (in $atm$)

In a $1.0 \, L$ vessel at $90 \, ^\circ C$,$0.2 \, mol$ of $H_{2(g)}$ and $2.0 \, mol$ of $S_{(s)}$ are mixed. For the reaction $H_{2(g)} + S_{(s)} \rightleftharpoons H_2S_{(g)}$; $K_p = 6.8 \times 10^{-2}$,the partial pressure of $H_2S_{(g)}$ at equilibrium will be ............ $atm$.

For the reaction $A + B \rightleftharpoons C + D$ at $250^\circ C$ in a $1 \ L$ vessel,the initial concentration of $A$ is $3$ and $B$ is $n$. If the equilibrium concentration of $C$ is equal to the equilibrium concentration of $B$,what is the equilibrium concentration of $D$?

For a reaction,$A \rightleftharpoons P$,the plots of $[A]$ and $[P]$ with time at temperatures $T_1$ and $T_2$ are given below. If $T_2 > T_1$,the correct statement$(s)$ is (are) (Assume $\Delta H^{\ominus}$ and $\Delta S^{\ominus}$ are independent of temperature and ratio of $\ln K$ at $T_1$ to $\ln K$ at $T_2$ is greater than $T_2 / T_1$. Here $H, S, G$ and $K$ are enthalpy,entropy,Gibbs energy and equilibrium constant,respectively.)
$(A)$ $\Delta H^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(B)$ $\Delta G^{\ominus} < 0, \Delta H^{\ominus} > 0$
$(C)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(D)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} > 0$