Consider that an ideal gas ($n$ moles) is expanding in a process given by $P = f(V)$,which passes through a point $(V_0, P_0)$. Show that the gas is absorbing heat at $(P_0, V_0)$ if the slope of the curve $P = f(V)$ is larger than the slope of the adiabatic curve passing through $(P_0, V_0)$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) For an ideal gas,the heat absorbed is given by $dQ = dU + dW = nC_V dT + P dV$.
Since $PV = nRT$,we have $T = \frac{PV}{nR} = \frac{f(V)V}{nR}$.
Differentiating with respect to $V$,we get $dT = \frac{1}{nR} [f(V) + V f'(V)] dV$.
Substituting this into the heat equation: $dQ = n C_V \left( \frac{f(V) + V f'(V)}{nR} \right) dV + f(V) dV$.
Using $C_V = \frac{R}{\gamma - 1}$,we get $dQ = \left( \frac{f(V) + V f'(V)}{\gamma - 1} + f(V) \right) dV$.
For the gas to absorb heat,$dQ > 0$ for $dV > 0$.
This requires $\frac{f(V) + V f'(V)}{\gamma - 1} + f(V) > 0$.
Simplifying,$f(V) + V f'(V) + (\gamma - 1)f(V) > 0$,which leads to $\gamma f(V) + V f'(V) > 0$.
Rearranging,$f'(V) > -\gamma \frac{f(V)}{V}$.
The slope of the adiabatic curve is given by $\frac{dP}{dV} = -\gamma \frac{P}{V}$.
Thus,the condition for heat absorption is that the slope of the process curve $f'(V)$ must be greater than the slope of the adiabatic curve $-\gamma \frac{P_0}{V_0}$.

Explore More

Similar Questions

Three moles of an ideal gas undergo a cyclic process $ABCA$ as shown in the figure. The pressure, volume, and absolute temperature at points $A, B,$ and $C$ are respectively $(P_1, V_1, T_1)$, $(P_2, 3V_1, T_1)$, and $(P_2, V_1, T_2)$. Then the total work done in the cycle $ABCA$ is (where $R$ is the universal gas constant).

The ratio of the specific heat capacities of a gas is $1.5$. When the gas undergoes an adiabatic process, its volume is doubled and its pressure becomes $P_1$. When the gas undergoes an isothermal process, its volume is doubled and its pressure becomes $P_2$. If $P_1 = P_2$, what is the ratio of the initial pressures of the gas when it undergoes adiabatic and isothermal processes?

Two gases have the same initial pressure,volume,and temperature. They expand to the same final volume,one adiabatically and the other isothermally. Which of the following statements is correct regarding the final state?

Difficult
View Solution

The following figure shows the $P-T$ graph for four processes $A, B, C,$ and $D$. Select the correct alternative.

Two moles of a monoatomic ideal gas is confined in a container and is heated such that its temperature increases by $10\,^{\circ}C$. The approximate change in its internal energy is ..... $J$. $(R = 8.31\, J/mol\cdot K)$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo