If the reaction is started with $NH_4COONH_{2(s)}$ and the equilibrium mixture has a total pressure of $3 \ atm$,then the $K_P$ for the reaction $NH_4COONH_{2(s)} \rightleftharpoons 2NH_{3(g)} + CO_{2(g)}$ is ..... $atm^3$.

In the reaction $2P_{(g)} + Q_{(g)} \rightleftharpoons 3R_{(g)} + S_{(g)}$,if $2 \text{ moles}$ of each $P$ and $Q$ are taken initially in a $1 \text{ L}$ flask,which of the following is true at equilibrium?

Ethyl acetate is formed by the reaction between ethanol and acetic acid and the equilibrium is represented as:
$CH_3COOH_{(l)} + C_2H_5OH_{(l)} \longleftrightarrow CH_3COOC_2H_{5(l)} + H_2O_{(l)}$
$(i)$ Write the concentration ratio (reaction quotient),$Q_c$,for this reaction (note: water is not in excess and is not a solvent in this reaction).
$(ii)$ At $293 \ K$,if one starts with $1.00 \ mol$ of acetic acid and $0.18 \ mol$ of ethanol,there is $0.171 \ mol$ of ethyl acetate in the final equilibrium mixture. Calculate the equilibrium constant.
$(iii)$ Starting with $0.5 \ mol$ of ethanol and $1.0 \ mol$ of acetic acid and maintaining it at $293 \ K$,$0.214 \ mol$ of ethyl acetate is found after sometime. Has equilibrium been reached?

Consider the following reversible first-order reaction of $X$ at an initial concentration $[X]_{0}$. The values of the rate constants are $K_{f} = 2 \ s^{-1}$ and $K_{b} = 1 \ s^{-1}$.
$X \underset{K_{b}}{\stackrel{K_{f}}{\rightleftharpoons}} Y$
Which of the following plots correctly represents the concentration of $X$ and $Y$ as a function of time?

Nitric oxide reacts with $Br_{2}$ and gives nitrosyl bromide as per the reaction given below:
$2 NO_{(g)} + Br_{2(g)} \longleftrightarrow 2 NOBr_{(g)}$
When $0.087 \ mol$ of $NO$ and $0.0437 \ mol$ of $Br_{2}$ are mixed in a closed container at constant temperature,$0.0518 \ mol$ of $NOBr$ is obtained at equilibrium. Calculate the equilibrium amount of $NO$ and $Br_{2}$.

Reaction between $N_{2}$ and $O_{2}$ takes place as follows:
$2 N_{2(g)} + O_{2(g)} \longleftrightarrow 2 N_{2}O_{(g)}$
If a mixture of $0.482 \ mol$ of $N_{2}$ and $0.933 \ mol$ of $O_{2}$ is placed in a $10 \ L$ reaction vessel and allowed to form $N_{2}O$ at a temperature for which $K_{c} = 2.0 \times 10^{-37}$,determine the composition of the equilibrium mixture.