Select the correct statement:

  • A
    Pure chloroform gives a precipitate with $aq. AgNO_3$.
  • B
    Chloroform is used as an analgesic.
  • C
    Iodoform is an anesthetic.
  • D
    $Ph-CO-CH_2-CO-Ph$ with $NaOH + I_2$ gives a yellow precipitate.

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The reaction of toluene with $Cl_2$ in the presence of $FeCl_3$ gives $X$ and the reaction in the presence of light gives $Y.$ Thus,$X$ and $Y$ are

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List-$I$ (Reaction) List-$II$ (Name of reaction)
$A$. $2C_6H_5X + 2Na \xrightarrow{\text{Dry Ether}} C_6H_5-C_6H_5 + 2NaX$ $I$. Lucas reaction
$B$. $ArN_2^{+} X^{-} \xrightarrow[HCl]{Cu} ArCl + N_2 \uparrow + CuX$ $II$. Finkelstein reaction
$C$. $C_2H_5Br + NaI \xrightarrow{\text{Acetone}} C_2H_5I + NaBr$ $III$. Fittig reaction
$D$. $(CH_3)_3COH \xrightarrow[ZnCl_2]{HCl} (CH_3)_3CCl + H_2O$ $IV$. Gatterman reaction

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Assertion : Alkylbenzene is not prepared by Friedel-Crafts alkylation of benzene.
Reason : Alkyl halides are less reactive than acyl halides.

Match the following lists:
List-$I$List-$II$
$(A)$ Benzene$1$. Phosgene
$(B)$ Ethylene$2$. Silver mirror
$(C)$ Acetaldehyde$3$. Mustard gas
$(D)$ Chloroform$4$. $(4n + 2) \pi$ electrons
$5$. Carbylamine

$C_3H_7I$ $(P)$ $\xrightarrow[\text{alc. } KOH]{\Delta}$ $Q$ $\xrightarrow{NBS}$ $R$ $\xrightarrow{KCN}$ $CH_2 = CH - CH_2 - CN$. $P$ can be:

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