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Write the chemical reactions of acetic acid $(CH_3COOH)$ with the following reagents:
$(i)$ Excess $Cl_2$ $+$ Red $P$ followed by $H_2O$
$(ii)$ Heating with sodalime $(NaOH + CaO)$
$(iii)$ Electrolysis of its sodium salt ($Kolbe's$ electrolysis)
$(iv)$ Heating with excess ammonia $(NH_3)$
$(v)$ Reaction with $PCl_5$
$(vi)$ Reaction with $PCl_3$
$(vii)$ Reaction with $SOCl_2$
$(viii)$ Heating with $P_2O_5$
$(ix)$ Reaction with $NaOH_{(aq)}$
$(x)$ Reaction with $NaHCO_{3_{(aq)}}$
$(xi)$ Reaction with $Na$ metal
$(xii)$ Reaction with $LiAlH_4$ / ether or $BH_3$
$(xiii)$ Reaction with ethanol $(C_2H_5OH)$ in the presence of $H_2SO_4$ or $HCl$ gas

Match List-$I$ with List-$II$.
List-$I$:
$(a)$ $\text{Benzene} \xrightarrow[\text{CuCl}]{\text{CO, HCl, Anhyd. AlCl}_3} \text{Benzaldehyde}$
$(b)$ $R-CO-CH_3 + NaOX \rightarrow$
$(c)$ $R-CH_2-OH + R'COOH \xrightarrow{\text{Conc. H}_2\text{SO}_4}$
$(d)$ $R-CH_2COOH \xrightarrow[(ii) H_2O]{(i) X_2/\text{Red P}} R-CH(X)COOH$
List-$II$:
$(i)$ $\text{Hell-Volhard-Zelinsky reaction}$
(ii) $\text{Gattermann-Koch reaction}$
(iii) $\text{Haloform reaction}$
(iv) $\text{Esterification}$
Choose the correct answer from the options given below.

The major product expected from the following reaction is:
$2-(\text{carbamoyl})-3-(\text{hydroxymethyl})-6-(\text{hydroxy})\text{benzoic acid} \xrightarrow{HCl_{(g)} / CCl_4} ?$

Match Column-$I$ with Column-$II$ :
| Column-$I$ | Column-$II$ |
| :--- | :--- |
| $(A)$ Cyclopentanone + $2,4-$$DNP$ $\xrightarrow{\text{mild } H^+}$ Cyclopentanone$-2,4-$$DNP$ derivative | $(P)$ Electrophilic substitution |
| $(B)$ $4-$phenyl$-2-$methylbutan$-2-$ol $\xrightarrow{\text{Conc. } H_2SO_4}$ $1,1-$dimethyl$-1,2,3,4-$tetrahydronaphthalene | $(Q)$ Nucleophilic substitution |
| $(C)$ $4-$chlorocyclohexanethiol $\xrightarrow{\text{Base}}$ $7-$thiabicyclo[$2.2$.$1$]heptane | $(R)$ Nucleophilic addition |

What is the major product of the above Friedel-Crafts reaction?

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