When an aqueous solution of copper $(II)$ sulphate is saturated with ammonia,the blue compound crystallises on evaporation. The formula of this blue compound is

  • A
    $[Cu(NH_3)_4]SO_4 \cdot H_2O$ (square planar)
  • B
    $[Cu(NH_3)SO_4]$ (tetrahedral)
  • C
    $[Cu(NH_3)_6]SO_4$ (octahedral)
  • D
    $[Cu(SO_4)(NH_3)_4]$ (octahedral)

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Which of the following pairs of compounds is planar?

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Match List $-I$ with List $-II$:
List $-I$ List $-II$
$A$. $[PtCl_4]^{2-}$ $I$. $sp^3d$
$B$. $BrF_5$ $II$. $d^2sp^3$
$C$. $PCl_5$ $III$. $dsp^2$
$D$. $[Co(NH_3)_6]^{3+}$ $IV$. $sp^3d^2$

$Mn^{2+}$ forms a complex with $Br^{-}$ ion. The magnetic moment of the complex is $5.92 \ B.M.$ What could not be the probable formula and geometry of the complex?

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Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
$(i)$ $[Fe(CN)_6]^{4-}$
$(ii)$ $[FeF_6]^{3-}$
$(iii)$ $[Co(C_2O_4)_3]^{3-}$
$(iv)$ $[CoF_6]^{3-}$

In the formation of $K_4[Fe(CN)_6]$,the hybridisation involved is

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