Which of the following orders is not correct?

  • A
    $[Co(H_2O)_6]^{+2} < [Fe(H_2O)_6]^{+3} < [Fe(CN)_6]^{-3}$ ($\Delta_0$ order)
  • B
    $[Fe(CN)_6]^{-4} > [Fe(CN)_6]^{-3}$ ($Fe-C$ bond length)
  • C
    $CN^- < CO$ ($\pi$-accepting tendency)
  • D
    $C_2H_4 > K[PtCl_3(C_2H_4)]$ ($C-C$ bond length)

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$0.001 \ mol$ of $Co(NH_3)_5(NO_3)(SO_4)$ was passed through a cation exchanger. The acid coming out of it required $20 \ mL$ of $0.1 \ M$ $NaOH$ for neutralization. Hence,the complex is:

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The correct option(s) about entropy $(S)$ is(are)
$[R =$ gas constant, $F =$ Faraday constant, $T =$ Temperature $]$
$(A)$ For the reaction, $M_{(s)} + 2H^{+}_{(aq)} \rightarrow H_{2(g)} + M^{2+}_{(aq)}$, if $\frac{dE_{cell}}{dT} = \frac{R}{F}$, then the entropy change of the reaction is $R$ (assume that entropy and internal energy changes in entropy and internal energy are temperature independent).
$(B)$ The cell reaction, $Pt_{(s)} \mid H_2(g, 1 \ bar) \mid H^{+}(aq, 0.01 \ M) \parallel H^{+}(aq, 0.1 \ M) \mid H_2(g, 1 \ bar) \mid Pt_{(s)}$, is an entropy driven process.
$(C)$ For racemization of an optically active compound, $\Delta S > 0$.
$(D)$ $\Delta S > 0$, for $[Ni(H_2O)_6]^{2+} + 3en \rightarrow [Ni(en)_3]^{2+} + 6H_2O$ (where $en =$ ethylenediamine).

Three arrangements are shown for the complex $[CoBr_2(NH_3)_2(en)]^{\oplus}$. Which one is the wrong statement?

When a metal rod $M$ is dipped into an aqueous colourless concentrated solution of compound $N$,the solution turns light blue. Addition of aqueous $NaCl$ to the blue solution gives a white precipitate $O$. Addition of aqueous $NH_3$ dissolves $O$ and gives an intense blue solution.
$1.$ The metal rod $M$ is
$(A)$ $Fe$ $(B)$ $Cu$ $(C)$ $Ni$ $(D)$ $Co$
$2.$ The compound $N$ is
$(A)$ $AgNO_3$ $(B)$ $Zn(NO_3)_2$
$(C)$ $Al(NO_3)_3$ $(D)$ $Pb(NO_3)_2$
$3.$ The final solution contains
$(A)$ $[Pb(NH_3)_4]^{2+}$ and $[CoCl_4]^{2-}$
$(B)$ $[Al(NH_3)_4]^{3+}$ and $[Cu(NH_3)_4]^{2+}$
$(C)$ $[Ag(NH_3)_2]^{+}$ and $[Cu(NH_3)_4]^{2+}$
$(D)$ $[Ag(NH_3)_2]^{+}$ and $[Ni(NH_3)_6]^{2+}$
Give the answer for questions $1$,$2$ and $3$.

Which of the following orders is not correct?

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